Hmm, you do any crafting? The midguard dwarf has the Master Smith EX ability. You get craft magic arms and armor, craft wonderous item, forge ring, and you are considered to have all the necessary prereq's to craft anything. It would be a decent form during down time.
I was also excited about the Curst from Lost Empires of Faerun, but it turns out to be a template. Unkillable EX means you can only be killed by total body destruction or to remove the curse that keeps it from dying. No undying curse so only full destruction would work.
Edit: Mock Divinity EX from the lilitu in fiendish codex 1 stats the lilitu casts spells as a 9th level cleric, but she uses her Cha for spell casting. The ability goes on to describe additional casting things she does, so I think you could use this to pick up spell casting.